Product ID:PRINCEP 4L
MSDS Date:12/19/1986
FSC:6840
NIIN:00F027607
MSDS Number: BQZTN

CIBA-GEIGY CORP AGRICULTURAL DIV

410 SWING RD
GREENSBORO, NC 27419
US

Emergency Phone: 800-334-9481 OR 919-292-7100

Info Phone: 800-334-9481 OR 919-292-7100

Cage: 0267X

CIBA-GEIGY CORP, AGRICULTURAL DIV.

18300 GREENSBORO, NC 27419 US

Telephone: 800-888-8372 OR 800-334-9481

Cage: 8K340

SIMAZINE, 2-CHLORO-4,6-BIS(ETHYLAMINO)-S-TRIAZINE

CAS: 122-34-9

RTECS: XY5250000

TRADE SECRET COMPONENT

ACGIH TLV: 125 MG/CUM

NUISANCE PARTICULATES

OSHA PEL 15 MG/CUM

ACGIH TLV: 10 MG/CUM

LD50 LC50 Mixture:ORAL LD50 (RAT): >5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION:
NOSE & THROAT IRRITATION. INGESTION: NAUSEA & VOMITING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: POISON, KIDNEY DAMAGE.

First Aid:EYES: FLUSH W/WATER, HOLDING EYELIDS APART. DON'T ATTEMPT TO
NEUTRALIZE W/CHEMICAL AGENTS. SKIN: WASH W/SOAP & WATER INCLUDING
HAIR & UNDER FINGERNAILS. DON'T ATTEMPT TO NEUTRALIZE W/CHEMICAL
AGENTS. INHALATION: REMOVE TO FRESH AIR. INGESTION: IF CONSCIOUS,
GIVE PLENTY OF WATER & INDUCE VOMITING. NEVER GIVE ANYTHING BY
MOUTH IF UNCONSCIOUS. GIVE ARTIFICIAL RESPIRATION IF BREATHING
STOPS. SEE SUPP

Extinguishing Media:DRY CHEMICALS, FOAM, CO2
Fire Fighting Procedures:WEAR FULL FACE SELF-CONTAINED BREATHING
APPARATUS & IMPERVIOUS CLOTHING. USE STANDARD ORGANIC CHEMICAL
FIREFIGHTING TECHNIQUES.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. COVER SPILL
W/ABSORBENT MATERIAL OR LIME. SWEEP UP & PLACE IN APPROVED
CHEMICAL WASTE CONTAINER. WASH SPILL W/WATER & STRONG DETERGENT.
ABSORB, COLLECT & PLACE IN CHEMICAL CONTAINER. FLUSH SPILL AREA
W/WATER.

Handling and Storage Precautions:STORE IN ACCORDANCE W/GOOD PESTICIDE
HANDLING PRACTICE. KEEP ALL FOOD IN SEPARATE AREA AWAY FROM
STORAGE/USE LOCATION OF CHEMICAL.
Other Precautions:PREVENT EATING, DRINKING, TOBACCO USAGE & COSMETIC
APPLICATION IN AREAS WHERE THERE IS POTENTIAL FOR EXPOSURE TO
MATERIAL. HANDLE IN WELL VENTILATED AREA. KEEP MATERIAL OUT OF
REACH OF CHILDREN.

Respiratory Protection:EXPOSURE FOR LONG PERIODS TO EXCESSIVE DUST
COULD OCCUR, WEAR APPROVED DUST OR PESTICIDE RESPIRATOR
Ventilation:ADEQUATE
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GLASSES OR GOGGLES
Other Protective Equipment:WATERPROOF BOOTS, CLOTHING & HAT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
FIRST AID (CONT'D): IF POISONING IS SUSPECTED, DON'T WAIT FOR SYMPTOMS
TO DEVELOP. IMMEDIATELY CALL POSION CONTROL CENTER. THERE IS NO
SPECIFIC ANTIDOTE IF INGESTED. LAVAGE STOMACH. A SUSPENSION OF TH
IRTY TO FIFTY GRAMS OF ACTIVATED CHARCOAL CAN BE LEFT IN STOMACH.
GIVE SUITABLE SALINE LAXATIVE & SUPPORTIVE THERAPY.

Boiling Pt:B.P. Text:>100C
Vapor Pres:1.5
Spec Gravity:1.14
Solubility in Water:8 MG/L
Appearance and Odor:LIGHT BROWN SUSPENSION, ODORLESS

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & BASES

Waste Disposal Methods:DON'T ALLOW WASH WATER TO CONTAMINATE WATER
SUPPLIES. DON'T REUSE CONTAINER. DISPOSE OF IN ACCORDANCE
W/FEDERAL, STATE, & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.